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You can start an unscheduled Live Meeting by using the Meet Now meeting option.
Step 1: Click Start.
Step 2: Click All Programs, point to Microsoft Office Live Meeting 2007, and then click Microsoft Office Live Meeting 2007.
Step 3: On the Welcome to Microsoft Office Live Meeting page, click Meet Now to start your unscheduled meeting.

Step 1: Once you have entered the Live Meeting client, click on the Attendees pane.
Step 2: In the Attendees pane, point to Invite, and then click By E-mail.

Step 3: An email message will appear with the Live Meeting details for your meeting.
Step 4: In the To box of the e-mail invitation, type the e-mail addresses for your participants, separating each address by a semi-colon.
Step 5: To send the invitation, click Send.
Screen shot of how to invite participants to your Meet Now meeting
Step 1: Invited participants will click on the meeting URL in the participant meeting invitation that they would have received from you as the chairperson.
Step 2: Participants to enter their Display Name, the Meeting ID, and Meeting Key (if required to join the meeting).
Step 3: Participants follow the same audio instructions as you.